Phase Equilibrium of NaNO3/KNO3 in Glycerol + H2O Mixed Solvent System at 288.15 K and 298.15 K

نویسندگان

  • H. - Y. Zhang
  • W. - W. Zhu
  • G. - L. Qin
  • Z. Wei
چکیده

“Salting out effect” means that the addition of an organic solvent to an aqueous solution of a salt will reduce the solubility of salts and thus induce its precipitation.1 Therefore, the investigations of the physicochemical properties of inorganic salts in organic solvents – water, such as solubility data together with density, refractive index and so on, are of great scientific importance. Various systems of salt and mixed solvent systems have been investigated to assess the potential applicability of such method as a technique for separation of salts. Many of the reports focus on systems composed of alkaline metal chlorides, alcohols, and water. For example, the properties of systems of alcohol (propan-1-ol, propan-2-ol, pentan-2-ol, pentan-3-ol, 2-methylbutan-2-ol, 2-methylbutan-1-ol, and pentan-1-ol) + MCl (M = Na, K) + water were systematically studied by Gomis et al.2–5 Moreover, physicochemical properties of NaNO3 + H2O + poly(ethylene glycol),6 KNO3 + H2O + propan-2-ol,7 and LiNO3 in organic solvent (methanol, ethanol, propan-1-ol, propan-2-ol and butan-1-ol)8 were reported.

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تاریخ انتشار 2014